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#1 2008-03-19 18:41:59

Daryl560
New Member
Registered: 2008-03-19
Posts: 3

Carnot Engine

Hi all,
I have a perplexing problem.
The Carnot engine relies on 2 isothermal and 2 adiabatic processes.
In the sequence, the first isothermal and first adiabatic processes produce work(gas expansion), while the second isothermal and adiabatic processes require work to be put back in(gas compression). the theory being that the second 2 processes use less work than the first 2, so there is net output of work and everyone is happy(except those that thought they could get decent efficiency)

My problem is this. the Carnot Theorem states that no heat engine can be more efficient than the Carnot engine.
Consider a system that has a single cylinder(and piston) with an enclosed volume of gas. If the gas is heated by one isothermal process, creating as much work out as heat input to the system(by definition) and then the second isothermal process retraced the first back to initial conditions then the second isothermal process would output the same amount of work. Effectively providing power on the push and return strokes. This system would be 100% efficient wouldn't it? regardless of deltaT for hot and cold reservoirs?

If this is true then isn't it more efficient than the carnot Engine?

Thanks for any who share their thoughts on this

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#2 2008-03-19 21:16:44

Chris
Assistant Professor
From: Longwood University
Registered: 2004-09-30
Posts: 747
Website

Re: Carnot Engine

Consider a system that has a single cylinder(and piston) with an enclosed volume of gas. If the gas is heated by one isothermal process, creating as much work out as heat input to the system(by definition) and then the second isothermal process retraced the first back to initial conditions then the second isothermal process would output the same amount of work. Effectively providing power on the push and return strokes. This system would be 100% efficient wouldn't it? regardless of deltaT for hot and cold reservoirs?

The work done in that process would be zero. You can very quickly calculate the work done for any PV process by taking the area enclosed by the path. In the case you describe, that area would be zero. Therefore, the efficiency would be zero.

The proof that the Carnot cycle is the most efficient possible cycle is based on the fact that both the isothermal and adiabatic processes are quasi-static and what is called Kelvin's principle (which is really just a different way of stating the 2nd Law).


Chemists are physicists who don't do math. smile

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#3 2008-03-20 17:52:40

Daryl560
New Member
Registered: 2008-03-19
Posts: 3

Re: Carnot Engine

Thanks Chris
I realise that the area enclosed is zero when, as is the case for the Carnot Engine, the last of the four stages is stated as "work done on the gas"
This is the bit that i don't understand. The area enclosed is actually the area under the heat addition process BC minus the area under the heat extraction process DA(please refer to diagrams http://hyperphysics.phy-astr.gsu.edu/Hb … yc.html#c5). What I'm asking is why, for the purposes of calculating the efficiency, that the heat extraction process work is negative?

I understand that in the heat addition process, the gas does work on the piston. This is useful work. But in the heat extraction process, the work is done on the gas, but not by the piston. the piston surely doesn't need to be actively pushed back because the atmosphere does that job. If you take a cylinder at V2 and P1 and then remove heat, then the piston will be pushed back to V1 to keep P1 equal to atmospheric if P1 = atmospheric to start with.

So if you remove heat from the cylinder in this way then you can also extract useful work from the piston. ie the gas pushes the piston in the heating process which pushes the cam and then the atmosphere pushes the piston in the heat removal process, which pulls the cam.

So for the purposes of how much total work is done on the cam, why isn't the DA work added and not subtracted in the efficiency calculation?

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#4 2008-03-21 13:22:13

Chris
Assistant Professor
From: Longwood University
Registered: 2004-09-30
Posts: 747
Website

Re: Carnot Engine

Daryl560 wrote:

What I'm asking is why, for the purposes of calculating the efficiency, that the heat extraction process work is negative?

Think about the definition of work:

LaTeX Image

If we think about the work on the gas by the piston, then during compression the force by the gas on the piston would face "up" and the displacement of the piston would be "down". Therefore LaTeX Image equals 180 degrees, and LaTeX Image.

Similarily for expansion, the force by the gas on the piston would point "up" and the displacement of the piston would be "up". So LaTeX Image.

If we think about the work on the piston by the gas, then we get the opposite.

(BTW, the PV diagram you reference is not for the Carnot cycle.)

I think what you're trying to do is mix up your works. You want to consider the work on the gas by the piston for the expansion, and the work on the piston by the gas for the compression. This is almost like saying that if I push on the wall with 10 N of force, I know the wall pushes back with 10 N of force, therefore the total force is 20 N. When we talk about forces and work, the notation "on X by Y" is very important.

I understand that in the heat addition process, the gas does work on the piston. This is useful work. But in the heat extraction process, the work is done on the gas, but not by the piston. the piston surely doesn't need to be actively pushed back because the atmosphere does that job. If you take a cylinder at V2 and P1 and then remove heat, then the piston will be pushed back to V1 to keep P1 equal to atmospheric if P1 = atmospheric to start with.

I think you are considering work by the atmosphere in one process while neglecting the negative work done by the atmosphere in the other.


Chemists are physicists who don't do math. smile

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#5 2008-03-23 02:34:29

Daryl560
New Member
Registered: 2008-03-19
Posts: 3

Re: Carnot Engine

This is almost like saying that if I push on the wall with 10 N of force, I know the wall pushes back with 10 N of force, therefore the total force is 20 N.

I think perhaps a closer annalogy would be pushing on a springy wall. I push on the wall with 10N and it deforms. While deforming, my hand moves distance d, and so work is done. If there were a plunger of a linear generator attached to my hand, with the generator body fixed in space, and the generator attached to a light bulb, then the movement of my hand with 10N for a distance d would result in the bulb glowing(ok, it's a really small bulb!)

Now after moving a distance d, my hand reaches the point where the elastic properties of the wall exert 10N back. the hand stops. But then if I cease to exert a force with my hand then the wall will push my hand back with 10N a distance d, and back to initial conditions. Again the plunger is moved and the bulb glows, be it with the reverse current. However my point is that work is done to the external system in both directions, in the case of the bulb, perhaps useful work.

I'm seeing the cylinder with enclosed gas and piston in the same way. When the pressure is higher inside then the gas does work on the piston, and yes I agree, also does work on the atmosphere. but the atmosphere at this point offers little resistance because it is at the lower pressure. So the bulk of the work can be harnessed.
In the reverse motion, the gas is the one with the lower pressure, so the atmosphere does the work and the gas does a small amount of work back in the form of resistance, but this is small compared to the work done on the piston by the atmosphere, so again it can be harnessed.

Two things strike me as important. if you take a stand-alone cylinder with enclosed gas and piston, you can get it to do useful work by adding heat.
If you take the same system and remove heat, you also can do useful work.
And ok, the work vector is in opposite directions in the two casses, but isn't the modulus of these two vectors the "useful" work and not the addition of positive and negative work?
To me it seems like AC current. One can't say that the negative part of the cycle should be subtracted from the positive part to obtain it's useful work

I mean I do understand that in the Carnot cycle  there is a certain loss of energy, that can't be convereted to work, because by necessity some of the energy from the hot source must end up in the cold sink, and so not all can be converted to work. But because of my thinking above, I can't understand how it's as simple as just subtracting the work in the second half of the cycle, from the first half. It seems it must be more complicated than that

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#6 2008-03-26 20:23:03

Chris
Assistant Professor
From: Longwood University
Registered: 2004-09-30
Posts: 747
Website

Re: Carnot Engine

Hmmm. I wrote a lengthy post about this and it didn't seem to stick. Strange.

I'll have to get back to you when I have more time. However, if you are going to do something useful with your bulb (like have it light up or heat something), then it requires a difference in temperature.


Chemists are physicists who don't do math. smile

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